2.01 Navigating the Periodic Table

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Del curso dictado por University of Kentucky

Chemistry

560 calificaciones

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University of Kentucky

Chemistry

560 calificaciones

This course is designed to cover subjects in advanced high school chemistry courses, correlating to the standard topics as established by the American Chemical Society. This course is a precursor to the Advanced Chemistry Coursera course. Areas that are covered include atomic structure, periodic trends, compounds, reactions and stoichiometry, bonding, and thermochemistry.

De la lección

Week 2

Once we understand the electronic structure, we will be able determine how the periodic table can be used to compare the elements according to atomic size and various energies. We will conclude by seeing how these trends can be used to predict chemical properties of the elements.

2.01 Navigating the Periodic Table 12:32

2.02 Monoatomic ions and electron configuration 9:22

2.02a Electron Configuration of Ions 7:12

2.03 Effective Nuclear Charge and atomic and ionic radii 23:22

2.03a Isoelectronic and Radii 4:15

2.04 Ionization Energy 14:29

2.04a Wavelength of light emitted from first excited state 7:07

2.04b Hydrogen-like atom of flourine 7:59

2.05 Electron Affinity 7:45

2.06 Properties of Representative Elements 23:48

Conoce a los instructores

Dr. Allison Soult
Lecturer
Chemistry
Dr. Kim Woodrum
Sr. Lecturer
Chemistry

As we begin our next unit, we'll be looking at the periodic table.

And we will be looking at the information that we can obtain about an.

An element, based upon its location on the periodic table.

Now, when the periodic table was laid out and

designed, they did not know anything about the electronic structure.

They only knew about their chemical and physical behavior.

And so they lined things up, in similar ways according to their similar behavior.

And now as we understand the electronic structure we see that these electrons, and

where they're located in the periodic table that give us information

about the way these elements will behave chemically, as well as physically.

So, let us begin with our first learning objective.

In our first learning objective we're going to be

looking at the connection between the electron configuration of an atom, and

where it is located on the periodic table.

Now, we have learned to use a periodic table to come up with

the electron configuration, but we really haven't looked at the similarities of

elements within a group, within a family.

Let's look at a particular family, we're going to start by looking at the Halogens.

So we're going to do the electron configuration of each of the Halogens,

let's begin with Fluorine, so we look at Fluorine,

what I want you to do is maybe pause the video and pull out a periodic table and.

Try to do the electron configuration of each of these as we go through it.

So you find the noble gas before fluorine, and work your way over to it.

And you come up with Helium 2s2 2p5.

Then we'll do it for Chlorine.

Okay, that'll be next.

Next to Halogen.

Well, if we do it's electron configuration the noble gas that comes before it,

is Neon.

So it's Neon 3s2 3p5.

And then we can do it for Bromine, and if we do it for Bromine the noble gas that

comes before Bromine is Argon, and we work our way over to the Bromine and

we have Argon 4s2 3d10 4p5.

So as we look down that family,

there we're going to see what they have in common.

And that is if you look at the highest principle quantum number n for these.

There's your n.

'Kay?

And you see how many electrons are in that with the highest n.

You see that there are 7 electrons located there.

And here we have an n that is 3 and if we look at all of those we have 7 electrons.

And if we look at Bromine,

while there is this d submerged in the middle between those s's and p's.

If we look at the highest n.

Okay?

Here.

We have again 2 plus 5.

We have 7 electrons.

In that value.

That highest in value.

So we see that all of these have something very much in common, for the Halogens.

If we look at a periodic table and

we find those Halogens, we will see a number associated above this family here,

that's the same as the number of electrons we saw in that.

So all of those will have that in common.

They will have seven electrons in that shell that.

That contains the highest in.

And this is going to be true for any one of these groups here.

Now, it only works for our representative elements.

We cannot do this, for any of the transition elements.

Okay, but it does work for those representative elements very, very nicely.

So, we notice the similarity in the families.

Okay, electron configuration causes these families to have.

The similar behavior, chemically and physically.

So within a group, because they have a similar electron configuration,

they are going to behave similarly.

So electrons that are written after that noble gas core,

are called the valence electrons, or the outer electrons.

For a family, or for that group as we go down,

they will all have the same number of these valance electrons.

And it's these valance electrons,

that are the ones that are involved in chemical bonding.

So when we start looking at the atoms combining into forming compounds,

we'll be utilizing those valance electrons.

And as we saw on the previous this periodic table, the group number for

those representative elements is equal to the number of valence electrons.

So that is an important piece of information to keep in mind.

You must keep in mind that it's for

the representative elements and not for the transition elements.

All right, so

we're going to learn some group names here, but just let me re-emphasize, okay?

The group number, right here is the number of valence electrons in those

representative elements, so if we wanted to know how many valence electrons 10 has,

we would find 10 on the periodic table.

Which is located right here, and we would go up to this number that has

the A associated with it, and we would know that 10 has 4 valence electrons.

So, we're gaining information about the periodic table from about the elements

from where they're located on the periodic table.

So, our periodic.

Table is a wonderful cheat sheet for us.

We'll always have access to it, or

you'll always have access to it when you take your exams, okay?

So there's some groups that we need to know the names of,

because I will use these names as we proceed through this unit.

And for the rest of our chemistry course.

The first one we want to make sure we know the name of is our Alkali Metals.

The Alkali Metals are this group right here.

The 1A family.

So sometimes you can just call them the 1A family, but they're the Alkali Metals.

The next is the.

The Alkaline Earth Metals.

The Alkaline Earth Metals are the 2A group, okay?

So those are the Alkaline Earth Metals.

Alkaline means basic, okay?

Something is alkaline and we're talking about acids versus bases,

they are basic in their properties, and that's where they got their name.

The next we have is the Noble Gases.

The Noble Gases are located right here,

that last group of representative elements.

We see that it has a 8 above them,

so have 8 valence electrons, and that is true for every element except for Helium.

Helium couldn't possibly have 8 valance electrons, because it only has 2 electrons

in it's entirety so Helium has 2 valance electrons, but everybody else

in that everybody else every other element in that group has 8 valance electrons.

Next we have the Halogens, Halogens are these here now you use that term at

the very beginning of our slides we went through Florine, Chlorine, Bromine and

did there electron configuration, but those are our Halogens.

Another thing that we need to make sure we know about periodic table,

is that we can locate things by the period they're located in.

So, as we go across, those are periods.

So that's the first period, this is the second period, this is the third period.

So if I were to ask you for a Halogen in the fourth period,

you'd be able to locate Bromine as a Halogen in the fourth period.

Valence electrons are in the shell.

Of that, that's equal to that number.

So when we did the electron configuration of Bromine,

Bromine we'll write it down here again, is argon okay, 4s2, 3d10, 4p5, okay?

We see that the number 4 is associated with that period number.

Okay, so use your periodic table, and

use what you learned without having to do the whole electron configuration.

Tell me how many valence electrons are in Calcium.

If you said 2, then you are correct.

If you didn't say 2, let's locate Calcium.

There it is.

There's the group number.

And so we have two valence electrons.

And it works, because it's a representative element and

not a transition element.

Now let's refresh our memories on

various locations of areas on the periodic table.

I've been using the term Representative Element and maybe.

Maybe you're not familiar with what that means.

Everything that is shaded in this similar color here,

are our Representative Elements.

And depending on what screen I have, it's kind of different colors.

But, Representative Elements are these elements here, 'kay?

The definition of it,

Representative Elements, comes from their electron configuration.

So they have incompletely filled s and p sublevels, okay?

So when we're dealing with the Representative Elements, their s and

p subshells, are incompletely filled to be in that category.

So you'd looked at the electron configuration, stopped and

did it for any one of those,

you would know that you were dealing with a Representative Element.

Now, we've already talked about the Noble Gasses, and we know what they are.

But, how are they defined in terms of their electron configuration?

Well, the Noble Gases have completely filled s and p, okay?

So the s, has two valence electrons and the p will have six valence electrons for

all the Noble Gases, so they stand alone as a unique feature of our periodic table,

because of their completely filled s and p subshells.

So the Representative Elements have incompletely filled s and p, but

the Noble Gases have completely s and p sub shells.

The next one are Transition Elements.

Now Transition Elements are these, and sometimes they're called Transition Metals

instead of Transition Elements, so we can change the name in there,

because they're all metals, that would be okay, what is unique about them?

So in terms of electron configuration,

what Transition Metals have is a d that's incompletely filled.

So it's got electrons in the d subshell, anywhere from 1 to 9, and that

gives them unique properties, and so they categorize them in all Transition Metals.

Now the Lanthanides are down here in the bottom,

remember we take them out of the periodic table.

They are located between here, and here in the periodic table.

Named after the element that comes before it.

Sometimes you will see it written down there with the series, but

there's the Lanthanide series and the Actinide series.

And what's unique about the Lanthanide series is that,

they will have electrons going into the f subshell.

And it will be the fourth subshell.

The Actinides will have them going in to the five f sub shell,

and they've got one little group of a few elements here.

They don't have a name.

We'll just call 'em the Zinc, Mercury and Cadmium group right here.

What is unique about them?

Well they all will have a 10 valance electrons.

So they won't be considered transition elements because, the fact that

their d subshell is completely filled up gives them unique properties.

Okay?

So, the way the periodic table is laid out,

and the way these elements are grouped together.

All come about based upon their electron configuration.

And we group them this way, because we can study them as a group,

and know something about every element in that group by studying the group itself.

That's a lot of what chemistry is about.

Chemistry is very, very often about taking things and putting them into categories.

And from that category, knowing things about the category, therefore you

know something about every piece of matter that fits into that category.

When we group things together we know things about that element, or about that

specific piece of matter, and here we're just grouping things according to their

location on the period table, according to their electronic configuration.

So this completes learning objective number one,

where we are examining the electron configuration, and

how the periodic table and the electron configuration kind of go hand in hand.

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